An Innovative Approach to Meteorite Analysis by Laser‐Induced Breakdown Spectroscopy          下载免费PDF全文

Giorgio S. Senesi  Gioacchino Tempesta  Paola Manzari  Giovanna Agrosì 《Geostandards and Geoanalytical Research》2016,40(4):533-541

An innovative approach of double pulse laser‐induced breakdown spectroscopy (DP‐LIBS) coupled with optical microscopy was applied to the characterisation and quantitative analysis of the Agoudal iron meteorite in bulk sample and in petrographic thin section. Qualitative analysis identified the elements Ca, Co, Fe, Ga, Li and Ni in the thin section and the whole meteorite. Two different methods, calibration‐free LIBS and one‐point calibration LIBS, were used as complementary methodologies for quantitative LIBS analysis. The elemental composition data obtained by LIBS were in good agreement with the compositional analyses obtained by traditional methods generally applied for the analysis of meteorites, such as ICP‐MS and EDS‐SEM. Besides the recognised advantages of LIBS over traditional techniques, including versatility, minimal destructivity, lack of waste production, low operating costs, rapidity of analysis, availability of transportable or portable systems, etc., additional advantages of this technique in the analysis of meteorites are precision and accuracy, sensitivity to low atomic number elements such as Li and the capacity to detect and quantify Co contents that cannot be obtained by EDS‐SEM.  相似文献   

Introduction     

Paola Malanotte-Rizzoli  Allan R. Robinson 《Deep Sea Research Part II: Topical Studies in Oceanography》1993,40(6)

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Magnesiochloritoid: Compressibility and high pressure structure refinement     

Paola Comodi  Marcello Mellini  Pier Francesco Zanazzi 《Physics and Chemistry of Minerals》1992,18(8):483-490

The response of magnesiochloritoid to pressure has been studied by single crystal X-ray diffraction in a diamond anvil cell, using crystals with composition Mg_1.3Fe_0.7Al₄Si₂O₁₀(OH)₄. The unit cell parameters decrease from a = 9.434 (3), b = 5.452 (2), c = 18.136 (5) Å, β = 101.42° (2) (1 bar pressure) to a = 9.370 (7), b = 5.419 (5), c = 17.88 (1) Å, β = 101.5° (1) (42 kbar pressure), following a slightly anisotropic compression pattern (linear compressibilities parallel to unit cell edges: β _a = 1.85, β _b = 1.74, β_c = 3.05 × 10^?4 kbar^?1) with a bulk modulus of 1480 kbar. Perpendicular to c, the most compressible direction, the crystal structure (space group C2/c) consists of two kinds of alternating octahedral layers connected via isolated SiO₄ tetrahedra. With increasing pressure the slightly wavy layer [Mg_1.3Fe_0.7AlO₂(OH)₄] tends to flatten. Furthermore, the octahedra in this layer, with all cations underbonded, are more compressible than the octahedra in the (A1₃O₈) layer with slightly overbonded aluminum. Comparison between high-pressure and high-temperature data yields the following equations: $$\begin{gathered} a_{P,T} = 9.434{\text{ }}{\AA} - 174 \cdot 10^{ - 5} {\text{ }}{\AA}{\text{kb}}^{{\text{ - 1}}} \cdot P \hfill \\ {\text{ }} + 9 \cdot 10^{ - 5} {\text{ }}{\AA}^\circ C^{ - 1} \cdot (T - 25^\circ C) \hfill \\ b_{P,T} = 5.452{\text{ }}{\AA} - 95 \cdot 10^{ - 5} {\text{ }}{\AA}{\text{kb}}^{{\text{ - 1}}} \cdot P \hfill \\ {\text{ }} + 5 \cdot 65 \cdot 10^{ - 5} {\text{ }}{\AA}^\circ C^{ - 1} \cdot (T - 25^\circ C) \hfill \\ c_{P,T} = 18.136{\text{ }}{\AA} - 549 \cdot 10^{ - 5} {\text{ }}{\AA}{\text{kb}}^{{\text{ - 1}}} \cdot P \hfill \\ {\text{ }} + 16 \cdot 2^{ - 5} {\text{ }}{\AA}^\circ C^{ - 1} \cdot (T - 25^\circ C) \hfill \\ \end{gathered} $$ with P in kbar and T in °C. These equations indicate that the unit cell and bond geometry of magnesiochloritoid at formation conditions do not differ greatly from those at the outcrop conditions, e.g. the calculated unitcell volume is 917.3 ų at P = 16 kbar and T=500 °C, whereas the observed volume at room conditions is 914.4 ų. In addition, they show that the specific gravity increases from formation at depth to outcrop at surface conditions.  相似文献   

Coastal uplift rate at Matanzas (Cuba) inferred from MIS5e phreatic overgrowths on speleothems          下载免费PDF全文

Jo De Waele  Ilenia M. D'Angeli  Nicola Tisato  Paola Tuccimei  Michele Soligo  Joaquín Ginés  Angel Ginés  Joan J. Fornós  Igor M. Villa  Esteban R. Grau González  Stefano M. Bernasconi  Tomaso R. R. Bontognali 《地学学报》2017,29(2):98-105

Many morphological elements in Cuba's landscape (e.g. marine terraces, tidal notches) demonstrate that coastal uplift has taken place, but the rate at which this occurs is not known. Carbonate phreatic overgrowths on speleothems have been found in a cave in Central North Cuba, ~1 km from the present coastline at 16 m asl. They form exceptional and unique mushroom‐shaped speleothems and balconies decorating the walls of the rooms. These phreatic overgrowths on speleothems (POS) formed at the oscillating air–water interface in sea‐level controlled anchialine lakes. U/Th dating of these overgrowths suggests ages that are compatible with the Marine Isotope Stage 5e (i.e. 130–115 ka). These POS have fixed this sea‐level highstand and demonstrate that this part of Cuba has been subjected to a much lower uplift rate than previously reported, that is, less than 0.1 mm/year since the last interglacial.  相似文献   

Reply to comment on ‘Insights from the Mw 6.3 2009 L’Aquila earthquake (Central Apennines) – unveiling new seismogenic sources through their surface signatures: the adjacent San Pio Fault’     

Daniela Di Bucci  Paola Vannoli  Pierfrancesco Burrato  Umberto Fracassi  Gianluca Valensise 《地学学报》2011,23(6):421-423

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Diel microbial variations at a coastal Northern Adriatic station affected by Po River outflows     

Mauro Celussi  Alessandro Paoli  Fabrizio Bernardi Aubry  Mauro Bastianini  Paola Del Negro 《Estuarine, Coastal and Shelf Science》2008

Diel sampling was performed during an early spring survey in the Northern Adriatic Sea at a coastal station off the Po River delta. Samples were taken every 6 h at spring tide maxima and minima in the sub-superficial layer, at the maximum fluorescence depth (∼3 m). Variations in microbial community structure and its processes were assessed by considering heterotrophic bacteria, picocyanobacteria, viruses, exoenzymatic activities, microphytoplankton, nanoplankton and bacterial/cyanobacterial Denaturing Gradient Gel Electrophoresis (DGGE) profiles. A considerable diatom bloom, mostly supported by Skeletonema marinoi was detected. All microbial parameters except viruses, showed a sinusoidal trend with a 12 h period; only picocyanobacteria expressed relative maxima during high tide, showing a phase in opposition to the other parameters. No substantial changes in DGGE band patterns were detected. Even though the results showed bacterial activities to be influenced by the phytoplankton bloom, all microbial parameters' diel trends (except viruses) preferentially followed the tidal fluctuation rather than the light:dark cycle.  相似文献   

Distribution and population structure of the fish Helicolenus dactylopterus dactylopterus (Delaroche, 1809) in the Central Mediterranean (Southern Tyrrhenian Sea)     

Laura Pirrera  Teresa Bottari  Barbara Busalacchi  Daniela Giordano  Larissa Modica  Anna Perdichizzi  Francesco Perdichizzi  Adriana Profeta  & Paola Rinelli 《Marine Ecology》2009,30(S1):161-174

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Recolonization patterns of benthic assemblages after relict sand dredging in the central Tyrrhenian sea     

Marco Loia  Paola La Valle  Loretta Lattanzi  Barbara La Porta  Monica Targusi  Luisa Nicoletti 《Marine Ecology》2020,41(6):e12615

Recolonization patterns of benthic assemblages after relict sand dredging were investigated in an area offshore of Capo d’Anzio (central Tyrrhenian Sea). Surveys were performed before, during, and after dredging in 2007. Sampling stations were located within and outside the dredging site in water depths between 40 and 56 m. Defaunation due to sand extraction was the main impact observed in the inner stations and in stations located in proximity of the dredging site. At the inner stations, 9 months after dredging, a significant increase in species richness and diversity was observed: the sediment removal led to an increase of the sandy sediment fraction, favouring the settlement of sabulicolous species. A decrease in number of individuals and species was also observed in most of the outer stations, probably due to fine sediment redeposition. Recolonization of macrobenthic assemblages was essentially achieved at inner stations both in terms of abundance and species richness, while at outer stations it was still in progress. Results of this study, providing a picture of recovery times and processes in the Tyrrhenian Sea, could be used to develop predictions of the effects of future offshore sand dredging projects in comparable areas. Monitoring programs and research have a key role to provide a more detailed overview of biological recovery processes and times in different regions and with different dredging intensity.  相似文献   

Hydrothermal dolomitization in platform and basin carbonate successions during thrusting: A hydrocarbon reservoir analogue (Mesozoic of Venetian Southern Alps,Italy)     

Paola Ronchi  Daniele Masetti  Stefano Tassan  Davide Camocino 《Marine and Petroleum Geology》2012,29(1):68-89

The Early Jurassic dolomitized carbonates in the Venetian Alp, represent a surface analogue of the hydrocarbon exploration targets in Adriatic offshore and Po Plain, Italy. Dolomitization affected the carbonate platform of Monte Zugna Formation (Lower Jurassic) and the Neptunian dikes breccia in the pelagic Maiolica Formation (Uppermost Jurassic–Lower Cretaceous) improving the poro-perm characteristics. Petrography, stable isotope, strontium isotope ratio, trace element and fluid inclusion analyses were carried out on samples from the Monte Grappa Anticline, which is the direct analogue for subsurface. The petrographic analyses showed a first pervasive, replacement dolomitization phase (D1) followed by volumetrically less important dolomite cement precipitation phases (D2, D3, DS). The same, quite wide range of oxygen isotope (?9 to ?2‰ V-PDB) is observed in all dolomite types. The δ¹³C range is in the positive field of marine derived carbonate (from +0.5 to +3.2‰ PDB). The trace element analysis showed a slight enrichment in Fe and Mn contents in the Monte Zugna dolostones with respect the original limestone. The same dolomite precipitation temperature (up to 105 °C Th) was observed in the replacement and cement dolomites, suggesting a unique dolomitization event. This temperature, largely higher than the maximum burial temperature (about 50 °C), supports a hydrothermal origin of the dolomitizing fluids, which had a seawater to brackish composition. The data collected suggest a hydrothermal dolomitization occurring during to the South Alpine thrusting according to the “squeegee model”. The interpretation is consistent with the dolomitization model proposed for similar Jurassic successions in the Central Southern Alps. This study indicates that the deformed foreland and thrust fold belts carbonates in Po Plain and Adriatic offshore are suitable to be dolomitized, and therefore reflect an efficient hydrocarbon exploration play.  相似文献   

Solitary rossby waves over variable relief and their stability. Part II: numerical experiments     

Paola Malanotte Rizzoli   《Dynamics of Atmospheres and Oceans》1980,4(4):261-294

The barotropic, quasi-geostrophic vorticity equation describing large scale, rotating flows over zonal relief supports nonlinear permanent form solutions, namely nonlinear topographic Rossby waves. Through an analytical theory, these solutions have been shown to be neutrally stable to infinitesimal perturbations.Numerical algorithms, which necessarily truncate the infinite number of degrees of freedom of any continuum model to a finite number, are capable of reproducing the numerical equivalent of these form-preserving solutions. Moreover, these numerical solutions are shown to preserve their shape throughout the numerical experiment not only in the limit of small amplitude, but also for high amplitude (Rossby number → O(1)).Through numerical simulation, the stability analysis is carried far beyond the analytical limit of infinitesimal perturbations. The solutions maintain their stability in agreement with the analytical theory, up to perturbations having intensities almost of the same order as the solutions themselves. For higher-amplitude perturbations, the solutions break up and typical turbulent behavior ensues. The passage from wave-like to turbulent behavior, upon surpassing a critical perturbation value, can be observed in the sudden loss of phase locking of the permanent solution Fourier modes.  相似文献